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Effects of Particle Shape on Growth Dynamics at Edges of Evaporating Drops of Colloidal Suspensions

机译:颗粒形状对胶体悬浮液蒸发液滴边缘生长动力学的影响

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摘要

We study the influence of particle shape on growth processes at the edges of evaporating drops. Aqueous suspensions of colloidal particles evaporate on glass slides, and convective flows during evaporation carry particles from drop center to drop edge, where they accumulate. The resulting particle deposits grow inhomogeneously from the edge in two dimensions, and the deposition front, or growth line, varies spatiotemporally. Measurements of the fluctuations of the deposition front during evaporation enable us to identify distinct growth processes that depend strongly on particle shape. Sphere deposition exhibits a classic Poisson-like growth process; deposition of slightly anisotropic particles, however, belongs to the Kardar-Parisi-Zhang universality class, and deposition of highly anisotropic ellipsoids appears to belong to a third universality class, characterized by Kardar-Parisi-Zhang fluctuations in the presence of quenched disorder.
机译:我们研究了颗粒形状对液滴液滴生长过程的影响。胶体颗粒的水悬浮液在载玻片上蒸发,蒸发过程中的对流将颗粒从液滴中心带到液滴边缘,并在此积聚。产生的颗粒沉积物从边缘在两个维度上不均匀地生长,并且沉积前沿或生长线随时间而变化。通过测量蒸发过程中沉积前沿的波动,我们可以确定与颗粒形状密切相关的不同生长过程。球体沉积表现出经典的类似于泊松的生长过程。但是,具有各向异性的小颗粒沉积属于Kardar-Parisi-Zhang通用性类别,具有高度各向异性的椭球的沉积似乎属于第三类通用性,其特征是在存在淬灭紊乱的情况下Kardar-Parisi-Zhang波动。

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